Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Research output: Contribution to journalLetterResearchpeer-review

  • Jamie L. Manson
  • John A. Schlueter
  • Kerry E. Garrett
  • Paul A. Goddard
  • Tom Lancaster
  • Johannes S. Möller
  • Stephen J. Blundell
  • Andrew J. Steele
  • Isabel Franke
  • Francis L. Pratt
  • John Singleton
  • Bendix, Jesper
  • Saul H. Lapidus
  • Marc Uhlarz
  • Oscar Ayala-Valenzuela
  • Ross D. McDonald
  • Mary Gurak
  • Christopher Baines

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6 n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Original languageEnglish
JournalChemical Communications
Volume52
Issue number85
Pages (from-to)12653-12656
Number of pages4
ISSN1359-7345
DOIs
Publication statusPublished - 2016

ID: 169728412